Journal of Organic Chemistry p. 2794 - 2803 (2016)
Update date:2022-08-16
Topics:
Fu, Zhengjiang
Li, Zhaojie
Song, Yuanyuan
Yang, Ruchun
Liu, Yanzhu
Cai, Hu
Simple strategies for decarboxylative functionalizations of electron-deficient benzoic acids via using Cu(I) as promoter and electron-rich ones by employing Pd(II) as catalyst under aerobic conditions have been established, which lead to smooth synthesis of aryl halides (-I, Br, and Cl) through the decarboxylative functionalization of benzoic acids with readily available halogen sources CuX (X = I, Br, Cl), and easy preparation of benzonitriles from decarboxylative cyanation of aryl carboxylic acids with nontoxic and low-cost K4Fe(CN)6 under an oxygen atmosphere for the first time.
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