Paper
RSC Advances
method to simply and effectively intercalate the planar uorous
metal complexes into ZrP gallery. The Pd complexes immobi-
lized into ZrP have been successfully characterized by XRD, FT-
IR, TGA etc. The short uorous chain has been believed to help
to immobilize the neutral Pd complexes inside the galleries by
the uorous related H-bonding interactions. The Pd complex
immobilized ZrP was evaluated for Sonogashira/Heck reaction
in DMF. At ꢀthe end of each cycle, the product mixtures were
cooled to 0 C and centrifuged, and the catalyst was recovered
and reused. The results of immobilized Pd-catalyzed Sonoga-
shira/Heck reactions turned out to be efficient and recyclable.
2005, 17, 5606–5609; (c) E. Moghbelli, L. Sun, H. Jiang,
W. J. Boo and H.-J. Sue, Polym. Eng. Sci., 2009, 49, 483–490;
(d) L. Sun, J. Liu, S. R. Kirumakki, E. D. Schwerdtfeger,
R. J. Howell, K. Al-Bahily, S. A. Miller, A. Cleareld and
H.-J. Sue, Chem. Mater., 2009, 21, 1154–1161; (e) S. Wei,
M. Lizu, X. Zhang, J. Sampathi, L. Sun and M. F. Milner,
High Perform. Polym., 2013, 25, 25–32; (f) H.-J. Sue,
K. T. Gam, N. Bestaoui, N. Spurr and A. Cleareld, Chem.
Mater., 2004, 16, 242–249; (g) H.-J. Sue, K. T. Gam,
N. Bestaoui, A. Cleareld, M. Miyamoto and N. Miyatake,
Acta Mater., 2004, 52, 2239–2250; (h) W. J. Boo, L. Sun,
J. Liu, A. Cleareld, H.-J. Sue, M. J. Mullins and H. Pham,
Compos. Sci. Technol., 2007, 67, 262–269; (i) W. J. Boo,
L. Sun, J. Liu, E. Moghbelli, A. Cleareld, H.-J. Sue,
H. Pham and N. Verghese, J. Polym. Sci., Part B: Polym.
Phys., 2007, 45, 1459–1469; (j) W. J. Boo, L. Sun,
G. L. Warren, E. Moghbelli, H. Pham, A. Cleareld and
H.-J. Sue, Polymer, 2007, 48, 1075–1082.
Acknowledgements
N. Lu thanks the Ministry of Science and Technology of Taiwan
for the nancial supports. L. Sun acknowledges the support
from the National Science Foundation (Partnerships for
Research and Education in Materials, DMR-1205670), the Air
Force Office of Scientic Research (no. FA9550-12-1-0159), 14 (a) H. Hu, J. C. Martin, M. Xiao, C. S. Southworth, Y. Meng
Cottrell College Science Award from the Research Corporation
for Science Advancement (Award no.: 19770), and the Faculty
Large Grant from the University of Connecticut. L. Sun also
and L. Sun, J. Phys. Chem. C, 2011, 115, 5509–5514; (b)
H. Hu, J. C. Martin, M. Zhang, C. S. Southworth, M. Xiao,
Y. Meng and L. Sun, RSC Adv., 2012, 2, 3810–3815.
acknowledges the China Scholarship Council for offering Y. 15 (a) N. Lu, W. H. Tu, W. H. Chang, Z. W. Wu and H. C. Su, Acta
Zhou a scholarship to conduct research at University of
Connecticut.
Crystallogr., Sect. E: Struct. Rep. Online, 2011, 67, o355–o356;
(b) N. Lu, R. M. Ley, C. E. Cotton, W. C. Chung, J. S. Francisco
and E. I. Negishi, J. Phys. Chem. A, 2013, 117, 8256–8262; (c)
N. Lu, W. H. Tu, Y. S. Wen, L. K. Liu, C. Y. Chou and
J. C. Jiang, CrystEngComm, 2010, 12, 538–542; (d) N. Lu,
L. M. Hight, D. R. McMillin, J.-W. Jhuo, W.-C. Chung,
K.-Y. Lin, Y.-S. Wen and L.-K. Liu, Dalton Trans., 2014, 43,
2112–2119.
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