Russian Chemical Bulletin p. 1352 - 1356 (1993)
Update date:2022-08-17
Topics:
Terent'ev, A. B.
Gapusenko, S. I.
Vasil'eva, T. T.
The general kinetics of the addition of benzyl bromide to trimethylvinylsilane in the presence of the Fe(CO)5-DMF system has been studied.The reaction orders with respect to each reagent found in the study corresponding to a radical chain mechanism of the process.The metal-complex system takes part only in the initiation stage and only at a strictly defined ratio of the components. - Key words: benzyl bromide, trimethylvinylsilane, addition; radicals; metal-complex initiation; kinetics; mechanism.
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