Journal of Organometallic Chemistry p. C53 - C56 (1981)
Update date:2022-08-11
Topics:
Miyaura, Norio
Suzuki, Akira
The reaction of phenyl or 1-alkenyl iodides with 1-alkenyl-1,3,2-benzodioxaboroles readily obtainable via the hydroboration of 1-alkynes, gives the corresponding "head-to-tail" cross-coupling products, 2-phenyl-1-alkenes or 2-alkyl-1,3-alkadienes, in good yields.The reaction is effectively catalyzed by catalytic amounts of palladium compounds in the presence of triethylamine.
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