10.1002/cctc.202001158
ChemCatChem
COMMUNICATION
Scheme 4. Proposed mechanism for Mn-catalyzed alkene hydrogenation. The relative solvent-corrected Gibbs energies are shown in italics (kcal mol-1).
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We thank Dr. M. Roy (IAS) for HR-MS analysis and
acknowledge OIST for start-up funding and for access to the
high-performing cluster facility. We also thank Mr. Sébastien
Lapointe for collecting X-ray data for complex 2.
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Keywords: manganese • alkene hydrogenation • metal-ligand
cooperation • hydride complexes • P,N-donor ligand
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