1
388ꢀ
RongchangꢀLuoꢀetꢀal.ꢀ/ꢀChineseꢀJournalꢀofꢀCatalysisꢀ38ꢀ(2017)ꢀ1382–1389ꢀ
[15]ꢀ C.ꢀ Fang,ꢀC.ꢀ L.ꢀ Lu,ꢀ M.ꢀ H.ꢀ Liu,ꢀ Y.ꢀ L.ꢀZhu,ꢀY.ꢀ Fu,ꢀ B.ꢀ L.ꢀ Lin,ꢀACSꢀCatal.,ꢀ
4
.ꢀ ꢀ Conclusionsꢀ ꢀ
2016,ꢀ6,ꢀ7876–7881.ꢀ
[
[
[
[
16]ꢀ X.ꢀ F.ꢀ Liu,ꢀ C.ꢀ Qiao,ꢀ X.ꢀ Y.ꢀ Li,ꢀ L.ꢀ N.ꢀ He,ꢀ Greenꢀ Chem.,ꢀ 2017,ꢀ 19,ꢀ
Inꢀconclusion,ꢀweꢀhaveꢀdevelopedꢀaꢀsimpleꢀandꢀsustainableꢀ
1726–1731.ꢀ
pathwayꢀ forꢀ producingꢀ formamideꢀ derivativesꢀ byꢀ
N‐formylationꢀofꢀaminesꢀwithꢀCO ꢀandꢀhydrosilanesꢀunderꢀmildꢀ
17]ꢀ H.ꢀLü,ꢀQ.ꢀXing,ꢀC.ꢀT.ꢀYue,ꢀZ.ꢀQ.ꢀLei,ꢀF.ꢀW.ꢀLi,ꢀChem.ꢀCommun.,ꢀ2016,ꢀ
2,ꢀ6545–6548.ꢀ
2
5
conditions,ꢀbasedꢀonꢀaꢀzincꢀphthalocyanineꢀ(ZnPc)ꢀcatalystꢀandꢀ
aꢀstoichiometricꢀamountꢀofꢀDMF.ꢀOurꢀexperimentalꢀresultsꢀandꢀ
relatedꢀmechanisticꢀstudiesꢀindicateꢀthatꢀtheꢀcooperativeꢀeffectꢀ
betweenꢀ theseꢀ twoꢀ componentsꢀ promotedꢀ hydrideꢀ transferꢀ
18]ꢀ J.ꢀ Song,ꢀ B.ꢀ Zhou,ꢀ H.ꢀ Liu,ꢀ C.ꢀ Xie,ꢀ Q.ꢀ Meng,ꢀ Z.ꢀ Zhang,ꢀ B.ꢀ Han,ꢀ Greenꢀ
Chem.,ꢀ2016,ꢀ18,ꢀ3956–3961.ꢀ
19]ꢀ L.ꢀD.ꢀHao,ꢀY.ꢀF.ꢀZhao,ꢀB.ꢀYu,ꢀZ.ꢀZ.ꢀYang,ꢀH.ꢀY.ꢀZhang,ꢀB.ꢀX.ꢀHan,ꢀX.ꢀGao,ꢀ
Z.ꢀM.ꢀLiu,ꢀACSꢀCatal.,ꢀ2015,ꢀ5,ꢀ4989–4993.ꢀ
fromꢀhydrosilaneꢀtoꢀ CO
2
.ꢀ Strongꢀ polarꢀ additivesꢀ activatedꢀ theꢀ
[20]ꢀ M.ꢀHulla,ꢀF.ꢀD.ꢀBobbink,ꢀS.ꢀDas,ꢀP.ꢀJ.ꢀDyson,ꢀChemCatChem,ꢀ2016,ꢀ8,ꢀ
3338–3342.ꢀ
[21]ꢀ X.ꢀF.ꢀLiu,ꢀR.ꢀMa,ꢀC.ꢀQiao,ꢀH.ꢀCao,ꢀL.ꢀN.ꢀHe,ꢀChem.ꢀEur.ꢀJ.,ꢀ2016,ꢀ22,ꢀ
Si–Hꢀ bondꢀ withinꢀ theꢀ hydrosilaneꢀ viaꢀ solvationꢀ andꢀ polariza‐
tion,ꢀandꢀsimultaneouslyꢀactivatedꢀtheꢀN–Hꢀbondꢀofꢀtheꢀamine,ꢀ
therebyꢀ leadingꢀ toꢀ theꢀ increasedꢀ nucleophilicityꢀ ofꢀ theꢀ activeꢀ
16489–16493.ꢀ
[
[
[
[
22]ꢀ K.ꢀMotokura,ꢀN.ꢀTakahashi,ꢀD.ꢀKashiwame,ꢀS.ꢀYamaguchi,ꢀA.ꢀMiyaji,ꢀ
Zn‐Hꢀintermediates,ꢀwhichꢀpromotedꢀinsertionꢀofꢀCO .ꢀ
2
T.ꢀBaba,ꢀCatal.ꢀSci.ꢀTechnol.,ꢀ2013,ꢀ3,ꢀ2392–2396.ꢀ
23]ꢀ K.ꢀMotokura,ꢀN.ꢀTakahashi,ꢀA.ꢀMiyaji,ꢀY.ꢀSakamoto,ꢀS.ꢀYamaguchi,ꢀT.ꢀ
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Chem.ꢀSoc.,ꢀ2012,ꢀ134,ꢀ2934–2937.ꢀ
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GraphicalꢀAbstractꢀ
Chin.ꢀJ.ꢀCatal.,ꢀ2017,ꢀ38:ꢀ1382–1389ꢀ ꢀ ꢀ doi:ꢀ10.1016/S1872‐2067(17)62877‐8
Zincꢀphthalocyanineꢀasꢀanꢀefficientꢀcatalystꢀforꢀhalogen‐freeꢀ ꢀ
synthesisꢀofꢀformamidesꢀfromꢀaminesꢀviaꢀcarbonꢀdioxideꢀ ꢀ
hydrosilylationꢀunderꢀmildꢀconditionsꢀ
ꢀ
ꢀ
ꢀ
ꢀ
RongchangꢀLuo, XiaoweiꢀLin,JingꢀLu,XiantaiꢀZhou,HongbingꢀJiꢀ*ꢀ
SunꢀYat‐senꢀUniversity,ꢀGuangzhou;ꢀLiedeꢀExperimentalꢀSchoolꢀofꢀ
GuangzhouꢀTianheꢀHighꢀSchool,ꢀGuangzhou;ꢀSunꢀYat‐senꢀUniversity,ꢀ
Zhuhaiꢀ
ꢀ
ꢀ
Combinationꢀ ofꢀ zincꢀ phthalocyanineꢀ catalystꢀ andꢀ stoichiometricꢀ
dimethylꢀ formamideꢀ asꢀ aꢀ simpleꢀ approachꢀ toꢀ produceꢀ formamidesꢀ
fromꢀamines,ꢀCO ,ꢀandꢀhydrosilanesꢀunderꢀmildꢀconditions.ꢀ
2