Synthetic Communications p. 1425 - 1428 (1991)
Update date:2022-08-11
Topics:
Chauvin
Phenylphosphinic acid and dialkylsulfoxides are found to be alternative reagents for respectively the reducing reagent (formic acid) and the alkylating reagent (aldehyde) currently used for secondary amines N-alkylation. Primary amines do not react with this system, but phenylglycine is decarboxilated to benzylamine.
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