Journal of the Chemical Society - Faraday Transactions p. 2621 - 2630 (1992)
Update date:2022-08-04
Stothard, Nigel D.
Walker, Raymond W.
The oxidation of propene has been studied at a total pressure of 60 Torr between 400 and 520 deg C, and a detailed product analysis made in the initial stages of reaction over a wide range of mixture composition.Mechanisms for the formation of the products are discussed.The initial rates of formation of hexa-1,5-diene (HDE) and carbon monoxide are used to obtain A8 = 109.66 +/- 0.35 dm3 mol-1 s-1 and E8 = 78.6 +/- 4.5 kJ mol-1, the former giving
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