Journal of Organometallic Chemistry p. 137 - 142 (1995)
Update date:2022-08-11
Topics:
Taniguchi, Yuki
Horie, Shiro
Takaki, Ken
Fujiwara, Yuzo
The Cu(OAc)2/CF3COOH (TFA) system catalyzes the aminomethylation of gaseous alkanes such as propane and ethane with trimethylamine N-oxide to give N,N-dimethylisobutylamine (1) and N,N-dimethylpropylamine (7), respectively.The corresponding trifluoroacetates are also formed as by-products from the reactions of methane and propane. Keywords: Copper acetate; Aminomethylation; Amine N-oxide; C-H bond activation; C-C bond formation; Alkane
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