CP al et aa lsy es i ds oS c ni eo nt c ae d &j uTs et c mh na or lgo i ng sy
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ARTICLE
Journal Name
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Palmisano and S. Yurdakal, J. PhDoOtoI:c1h0e.m10.39P/hCo8tCoYb0i1o2l.84CA,
Conclusions
Herein, we could show that it is possible to improve the
2
012, 13, 224-245.
catalytic performance of Cu/CoO catalysts by changing the 13.
reaction environment. Different monofunctional alcohols
C. Minero, A. Bedini and V. Maurino, Appl. Catal. B-
Environ., 2012, 128, 135-143.
(
methanol, ethanol, n-propanol, and tert-butanol) in various 14.
A. Molinari, A. Maldotti, A. Bratovcic and G. Magnacca,
Catal. Today, 2013, 206, 46-52.
Y. Zhang, N. Zhang, Z. R. Tang and Y. J. Xu, Chem. Sci.,
solvent/water ratios were used to evaluate the improvement
in the glycerol oxidation reaction. Generally, the catalytic
activity relates linearly to the solvent polarity for the individual
co-solvents. The presence of methanol in contrast, resulted in
a diminished catalytic activity. These contradicting behaviors
can be explained by the formation of catalytically active
CuO(OH) that forms in the presence of ethanol,- n-propanol,
and tert-butanol, but not in the presence of methanol and by
15.
16.
17.
18.
2
013, 4, 1820-1824.
N. A. Hermes, A. Corsetti and M. A. Lansarin, Chem. Lett.,
014, 43, 143-145.
2
T. Jedsukontorn, V. Meeyoo, N. Saito and M. Hunsom,
Chem. Eng. J., 2015, 281, 252-264.
B. Zhou, J. Song, H. Zhou, L. Wu, T. Wu, Z. Liu and B. Han,
RSC Adv., 2015, 5, 36347-36352.
the disabled catalytic activity of the dissolved Cu species in 19.
methanol containing solvents. The results presented herein
give valuable insights of the effect of co-solvents on the crystal 20.
S. Schünemann, G. Dodekatos and H. Tüysüz, Chem.
Mater., 2015, 27, 7743-7750.
G. Dodekatos and H. Tüysüz, Catal. Sci. Technol., 2016, 6,
7
307-7315.
P. McMorn, G. Roberts and G. J. Hutchings, Catal. Lett.,
999, 63, 193-197.
structure of Cu/Co based catalysts and its activity towards the
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1.
2.
3.
4.
5.
6.
selective oxidation of glycerol, which can be employed to
improve the cost-efficiency of transition metal-based catalysts
by alteration of the solvent.
1
C. H. Zhou, J. N. Beltramini, C. X. Lin, Z. P. Xu, G. Q. Lu and
A. Tanksale, Catal. Sci. Technol., 2011, 1, 111-122.
G. Wu, X. Wang, Y. Huang, X. Liu, F. Zhang, K. Ding and X.
Yang, J. Mol. Catal. A-Chem., 2013, 379, 185-191.
Acknowledgements
G. M. Lari, C. Mondelli and J. Pérez-Ramır
2015, 5, 1453-1461.
C. Crotti and E. Farnetti, J. Mol. Catal. A-Chem., 2015, 396,
53-359.
́
ez, ACS Catal.,
We kindly acknowledge Bernd Spliethoff for the assistance in
HR-TEM analysis. We thank Marie Sophie Sterling and Heike
Hinrichs from the HPLC department for oxidation product
analysis and discussion. This work is supported by the Cluster
of Excellence RESOLV (EXC 1069) funded by the Deutsche
Forschungsgemeinschaft and Fonds der Chemischen Industrie
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X. Jin, M. Zhao, C. Zeng, W. J. Yan, Z. W. Song, P. S. Thapa,
B. Subramaniam and R. V. Chaudhari, ACS Catal., 2016, 6,
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576-4583.
2
2
7.
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X. L. Wang, G. D. Wu, X. F. Liu, C. F. Zhang and Q. B. Lin,
Catal Lett, 2016, 146, 620-628.
J. H. Xie, K. H. Yin, A. Serov, K. Artyushkova, H. N. Pham, X.
H. Sang, R. R. Unocic, P. Atanassov, A. K. Datye and R. J.
Davis, ChemSusChem, 2017, 10, 359-362.
(FCI).
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