Page 9 of 11
Journal of the American Chemical Society
environment of the microporous Cu-MOF for high propylene
2 2
performance in C H storage: synthesis and properties of a new
1
2
3
4
5
6
7
8
9
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
4
4
4
4
4
4
4
4
4
4
5
5
5
5
5
5
5
5
5
5
6
storage and efficient separation of light hydrocarbons. ACS Cent.
Sci. 2019, 5 (7), 1261–1268. DOI: 10.1021/acscentsci.9b00423
MOF-505 analogue with an inserted amide functional group.
Chem. Commun. 2016, 52 (45), 7241–7244. DOI:
10.1039/c6cc03198f
(27) Hu, T.-L.; Wang, H.; Li, B.; Krishna, R.; Wu, H.; Zhou, W.;
Zhao, Y.; Han, Y.; Wang, X.; Zhu, W.; Yao, Z.; Xiang, S.; Chen,
B. Microporous metal-organic framework with dual functionalities
for highly efficient removal of acetylene from ethylene/acetylene
(
14) Zhang, L.; Li, L.; Hu, E.; Yang, L.; Shao, K.; Yao, L.; Jiang,
K.; Cui, Y.; Yang, Y.; Li, B.; Chen, B.; Qian, G. Boosting
ethylene/ethane separation within copper(I)-chelated
metal−organic frameworks through tailor-made aperture and
specific π-complexation. Adv. Sci. 2019, 1901918. DOI:
10.1002/advs.201901918
(15) Li, H.; Li, L.; Lin, R.-B.; Zhou, W.; Zhang, Z.; Xiang, S.; Chen,
B. Porous metal−organic frameworks for gas storage and
separation: Status and challenges. EnergyChem. 2019, 1 (1),
mixtures. Nat. Commun. 2015,
6
(1), 7328. DOI:
10.1038/ncomms8328
(28) Lin, R.-B.; Li, L.; Wu, H.; Arman, H.; Li, B.; Lin, R.-G.; Zhou,
W.; Chen, B. Optimized separation of acetylene from carbon
dioxide and ethylene in a microporous material. J. Am. Chem. Soc.
2017, 139 (23), 8022–8028. DOI: 10.1021/jacs.7b03850
(29) Li, B.; Cui, X.; O’Nolan, D.; Wen, H.-M.; Jiang, M.; Krishna,
R.; Wu, H.; Lin, R.-B.; Chen, Y.-S.; Yuan, D.; Xing, H.; Zhou, W.;
Ren, Q.; Qian, G.; Zaworotko, M. J.; Chen, B. An ideal molecular
sieve for acetylene removal from ethylene with record selectivity
and productivity. Adv. Mater. 2017, 29 (47), 1704210–1704216.
DOI: 10.1002/adma.201704210
(30) Yao, Z.; Zhang, Z.; Liu, L.; Li, Z.; Zhou, W.; Zhao, Y.; Han,
Y.; Chen, B.; Krishna, R.; Xiang, S. Extraordinary separation of
acetylene containing mixtures with microporous metal-organic
frameworks with open O donor sites and tunable robustness
through control of the helical chain secondary building units.
Chem. -Eur. J. 2016, 22 (16), 5676–5683. DOI:
10.1002/chem.201505107
(31) Cui, X.; Chen, K.; Xing, H.; Yang, Q.; Krishna, R.; Bao, Z.;
Wu, H.; Zhou, W.; Dong, X.; Han, Y.; Li, B.; Ren, Q.; Zaworotko,
M. J.; Chen, B. Pore chemistry and size control in hybrid porous
materials for acetylene capture from ethylene. Science 2016, 353
(6295), 141–144. DOI: 10.1126/science.aaf2458
(32) Zhang, Y.-B.; Furukawa, H.; Ko, N.; Nie, W.; Park, H. J.;
Okajima, S.; Cordova, K. E.; Deng, H.; Kim, J.; Yaghi, O. M.
Introduction of functionality, selection of topology, and
enhancement of gas adsorption in multivariate metal−organic
framework-177. J. Am. Chem. Soc. 2015, 137 (7), 2641–2650. DOI:
10.1021/ja512311a
0
1
2
3
4
5
6
7
8
9
0
1
2
3
4
5
6
7
8
9
0
1
2
3
4
5
6
7
8
9
0
1
2
3
4
5
6
7
8
9
0
1
2
3
4
5
6
7
8
9
0
1
00006. DOI: 10.1016/j.enchem.2019.100006
(
16) Yang, S.; Ramirez-Cuesta, A. J.; Newby, R.; Garcia-Sakai, V.;
Manuel, P.; Callear, S. K.; Campbell, S. I.; Tang, C. C.; Schröder,
M. Supramolecular binding and separation of hydrocarbons within
a functionalized porous metal−organic framework. Nat. Chem.
2
(
014, 7 (2), 121–129. DOI: 10.1038/nchem.2114
17) Bachman, J. E.; Kapelewski, M. T.; Reed, D. A.; Gonzalez, M.
I.; Long, J. R. M (m-dobdc) (M = Mn, Fe, Co, Ni) Metal−organic
2
frameworks as highly selective, high-capacity adsorbents for
olefin/paraffin separations. J. Am. Chem. Soc. 2017, 139 (43),
15363–15370. DOI: 10.1021/jacs.7b06397
(18) Bloch, E. D.; Queen, W. L.; Krishna, R.; Zadrozny, J. M.;
Brown, C. M.; Long, J. R. Hydrocarbon separations in a
metal−organic framework with open iron(II) coordination sites.
Science
0.1126/science.1217544
19) Cadiau, A.; Adil, K.; Bhatt, P. M.; Belmabkhout, Y.; Eddaoudi,
2012,
335
(6076),
1606–1610.
DOI:
1
(
M. A metal−organic framework-based splitter for separating
propylene from propane. Science 2016, 353 (6295), 137–140. DOI:
10.1126/science.aaf6323
(
20) Wang, H.; Dong, X.; Colombo, V.; Wang, Q.; Liu, Y.; Liu,
W.; Wang, X.-L.; Huang, X.-Y.; Proserpio, D. M.; Sironi, A.; Han,
Y.; Li, J. Tailor-made microporous metal−organic frameworks for
the full separation of propane from propylene through selective size
exclusion. Adv. Mater. 2018, 30 (49), 1805088. DOI:
10.1002/adma.201805088
(21) Xiang, S.-C.; Zhang, Z.; Zhao, C.-G.; Hong, K.; Zhao, X.;
Ding, D.-R.; Xie, M.-H.; Wu, C.-D.; Das, M. C.; Gill, R.; Thomas,
K. M.; Chen, B. Rationally tuned micropores within enantiopure
metal−organic frameworks for highly selective separation of
acetylene and ethylene. Nat. Commun. 2011, 2 (1), 204. DOI:
(33) Yuan, S.; Qin, J.-S.; Li, J.; Huang, L.; Feng, L.; Fang, Y.;
Lollar, C.; Pang, J.; Zhang, L.; Sun, D.; Alsalme, A.; Cagin, T.;
Zhou, H.-C. Retrosynthesis of multi-component metal−organic
frameworks. Nat. Commun. 2018,
9
(1), 808. DOI:
10.1038/s41467-018-03102-5
1
0.1038/ncomms1206
(34) Yuan, S.; Chen, Y.-P.; Qin, J.-S.; Lu, W.; Zou, L.; Zhang, Q.;
Wang, X.; Sun, X.; Zhou, H.-C. Linker installation: engineering
pore environment with precisely placed functionalities in
zirconium MOFs. J. Am. Chem. Soc. 2016, 138 (28), 8912–8919.
DOI: 10.1021/jacs.6b04501
(35) Helal, A.; Yamani, Z. H.; Cordova, K. E.; Yaghi, O. M.
Multivariate metal−organic frameworks. Nat. Sci. Rev. 2017, 4 (3),
296–298. DOI:10.1093/nsr/nwx013
(36) Deng, H.; Doonan, C. J.; Furukawa, H.; Ferreira, R. B.; Towne,
J.; Knobler, C. B.; Wang, B.; Yaghi, O. M. Multiple functional
groups of varying ratios in metal−organic frameworks. Science
2010, 327 (5967), 846–850. DOI:10.1126/science.1181761
(37) Fan, W.; Wang, X.; Liu, X.; Xu, B.; Zhang, X.; Wang, W.;
(22) Hazra, A.; Jana, S.; Bonakala, S.; Balasubramanian, S.; Maji,
T. K. Separation/purification of ethylene from an
acetylene/ethylene mixture in
metal−organic framework. Chem. Commun. 2017, 53 (36), 4907–
910. DOI: 10.1039/c7cc00726d
23) Zhang, J.-P.; Chen, X.-M. Optimized acetylene/carbon dioxide
a
pillared-layer porous
4
(
sorption in a dynamic porous crystal. J. Am. Chem. Soc. 2009, 131
(15), 5516–5521. DOI: 10.1021/ja8089872
(24) Xu, H.; He, Y.; Zhang, Z.; Xiang, S.; Cai, J.; Cui, Y.; Yang,
Y.; Qian, G.; Chen, B. A microporous metal–organic framework
with both open metal and Lewis basic pyridyl sites for highly
selective C
temperature. J. Mater. Chem. A. 2013, 1 (1), 77–81. DOI
0.1039/c2ta00155a
25) Wen, H.-M.; Wang, H.; Li, B.; Cui, Y.; Wang, H.; Qian, G.;
Chen, B. A microporous metal-organic framework with lewis basic
nitrogen sites for high C storage and significantly enhanced
/CO separation at ambient conditions. Inorg. Chem. 2016, 55
2 2 4 2 2 2
H /CH and C H /CO gas separation at room
Wang, X.; Wang, Y.; Dai, F.; Yuan, D.; Sun, D. Regulating C
and CO storage and separation through pore environment
modification in a microporous Ni-MOF. ACS Sustainable Chem.
Eng. 2019, (2), 2134–2140. DOI:
10.1021/acssuschemeng.8b04783
2 2
H
1
(
2
7
2
H
2
C
2
H
2
2
(38) Chen, C.-X.; Wei, Z.-W.; Jiang, J.-J.; Zheng, S.-P.; Wang, H.-
P.; Qiu, Q.-F.; Cao, C.-C.; Fenske, D.; Su, C.-Y. Dynamic spacer
installation for multirole metal−organic frameworks: a new
direction toward multifunctional MOFs achieving ultrahigh
(15), 7214–7218. DOI: 10.1021/acs.inorgchem.6b00748
(
26) Zhang, M.; Li, B.; Li, Y.; Wang, Q.; Zhang, W.; Chen, B.; Li,
S.; Pan, Y.; You, X.; Bai, J. Finely tuning MOFs towards high
9
ACS Paragon Plus Environment