Journal of Organometallic Chemistry p. C45-C48 (1985)
Update date:2022-08-25
Topics:
Yamamoto, Yoshinori
Maruyama, Kazuhiro
The addition of a mixture of benzaldehyde and BF3·OEt2 to crotyl-organometallic reagents C4H7MLn (1) (M = Cu, Cd, Hg, Tl, Ti, Zr and V) produces predominantly the erythro homoallyl alcohol as well as the α-adduct, while without BF3·OEt2 the threo isomer is formed preferentially.
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