Phosphorus, Sulfur and Silicon and the Related Elements p. 332 - 340 (2009)
Update date:2022-08-29
Topics:
Kutuk, Halil
Ozturk, Seyhan
The acid-catalyzed hydrolysis of arylsulfonyl phthalimides was studied in aqueous solutions of sulfuric, perchloric, and hydrochloric acid at 35.0 ± 0.1C. Analysis of the data by the excess acidity method and activation parameters, as well as substituent and solvent isotope effects, indicate hydrolysis by an A-2 mechanism at low acidity. At higher acidities, a changeover to an A-1 mechanism is observed.
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Doi:10.1021/acs.joc.5b01376
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