Journal of Organic Chemistry p. 12189 - 12196 (2016)
Update date:2022-08-11
Topics:
Li, Chunsheng
Li, Jianxiao
An, Yanni
Peng, Jianwen
Wu, Wanqing
Jiang, Huanfeng
An efficient and practical palladium-catalyzed aerobic oxidative approach to afford functionalized 2-substituted quinolines in moderate to good yields from readily available allylbenzenes with aniline is developed. The present annulation process has high functional-group tolerance and high atom economy, making it a valuable and practical method in synthetic and medicinal chemistry. Moreover, this transformation is supposed to proceed through oxidation of allylic C-H functionalization to form C-C and C-N bonds in one pot.
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