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4 | CONCLUSIONS
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solvothermally.
A
novel UiO‐67‐FeCl3 catalyst was
synthesized by treating UiO‐67 with FeCl3·6H2O. Then The
UiO‐67‐FeCl3 was utilized as an efficient catalyst for the pro-
motion of aerobic oxidation of alcohols and aerobic benzylic
oxidations. The pyridine moiety of the UiO‐67‐FeCl3 catalyst
also served as an organic base, which allowed the amount of
basic additive to be reduced. A variety of alcohols were tested
and converted to their corresponding ketones in good yields.
In addition, similar reaction conditions were extended to the
aerobic oxidation of benzylic carbons to phenomes, using
molecular oxygen as the oxidant. The initial catalytic activity
of the UiO‐67‐FeCl3 catalyst was maintained after five con-
secutive reaction cycles. Hot filtration tests and ICP‐AES
analyses of the solution suggested the extremely low leakage
of the iron content during the reaction process. Further stud-
ies will aim at extending the applications of these MOF cata-
lysts to the oxidation of other substrates.
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ACKNOWLEDGEMENTS
We thank the Beijing Municipal Natural Science Foundation
(Grant No. 2172037), the National Natural Science Founda-
tion of China (No. 51503016) and Fundamental Research
Funds for the Central Universities (Grant No. FRF‐TP‐16‐
004A3) for financial support. Xin Shu also thanks BUCT
Fund for Disciplines Construction and Development
(No. XK1529) for financial support.
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