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loadings. e High-resolution TEM image of recovered 1. f lattice fringes of recovered 1. Ni (g) and Ru (h) EDS mapping for recovered 2. i
Fast Fourier Transform of electron diffraction data from recovered 1. j SAD pattern measurement of d-spacing for recovered 1.
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Wingad, R. L.; Gates, P. J.; Street, S. T. G.; Wass, D. F.,
Catalytic Conversion of Ethanol to n-Butanol Using Ruthenium P–N
Ligand Complexes. ACS Catal. 2015, 5 (10), 5822-5826.
ASSOCIATED CONTENT
Supporting Information
14.
Earley, J. H.; Bourne, R. A.; Watson, M. J.; Poliakoff, M.,
Continuous catalytic upgrading of ethanol to n-butanol and >C4 products
over Cu/CeO2 catalysts in supercritical CO2. Green Chem. 2015, 17 (5),
3018-3025.
Experimental procedures and analytical data for all compounds
(pdf).
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5.
Tseng, K.-N. T.; Lin, S.; Kampf, J. W.; Szymczak, N. K.,
Upgrading ethanol to 1-butanol with a homogeneous air-stable ruthenium
Corresponding Author
catalyst. Chem. Commun. 2016, 52 (14), 2901-2904.
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Xie, Y.; Ben-David, Y.; Shimon, L. J. W.; Milstein, D., Highly
*
Correspondence to: mdinca@mit.edu
Efficient Process for Production of Biofuel from Ethanol Catalyzed by
Ruthenium Pincer Complexes. J. Am. Chem. Soc. 2016, 138 (29), 9077-
9
080.
17.
Ho, C. R.; Shylesh, S.; Bell, A. T., Mechanism and Kinetics of
Notes
Ethanol Coupling to Butanol over Hydroxyapatite. ACS Catal. 2016, 6 (2),
39-948.
8.
The authors declare the following competing financial interest(s):
M.D. and C.N.N. are authors on a patent application describing
some of the results herein.
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Pang, J.; Zheng, M.; He, L.; Li, L.; Pan, X.; Wang, A.; Wang,
X.; Zhang, T., Upgrading ethanol to n-butanol over highly dispersed Ni–
MgAlO catalysts. J. Catal. 2016, 344, 184-193.
ACKNOWLEDGMENT
19.
Aitchison, H.; Wingad, R. L.; Wass, D. F., Homogeneous
Ethanol to Butanol Catalysis—Guerbet Renewed. ACS Catal. 2016, 6 (10),
This research was supported by funds from the Alan T. Waterman
Award conferred by the National Science Foundation to M.D.
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125-7132.
20.
Fu, S.; Shao, Z.; Wang, Y.; Liu, Q., Manganese-Catalyzed
(DMR-1645232). Fundamental studies of cation exchange in
Upgrading of Ethanol into 1-Butanol. J. Am. Chem. Soc. 2017, 139 (34),
1941-11948.
1. Wu, X.; Fang, G.; Liang, Z.; Leng, W.; Xu, K.; Jiang, D.; Ni, J.;
Li, X., Catalytic upgrading of ethanol to n-butanol over M-CeO2/AC
M=Cu, Fe, Co, Ni and Pd) catalysts. Catal. Commun. 2017, 100, 15-18.
2. Kulkarni, N. V.; Brennessel, W. W.; Jones, W. D., Catalytic
1
MOFs are supported through a CAREER grant to M.D. from the
National Science Foundation (DMR-1452612). We thank
Professor Ognjen Š. Miljanić for supplying ligand L2 for the
synthesis of Ni (OH) (OH ) (L2) and Dr. Robert Day for
8 4 2 2 6
performing XPS analysis.
2
(
2
Upgrading of Ethanol to n-Butanol via Manganese-Mediated Guerbet
Reaction. ACS Catal. 2018, 8 (2), 997-1002.
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