Tetrahedron Letters p. 7555 - 7558 (2000)
Update date:2022-08-11
Topics:
Gelman
Schumann
Blum
The intramolecularly stabilized alkyl and aryl aluminum complexes 1, 4 and 11, as well as the indium compounds 6, 9 and 10 cross-couple with a variety of chloroarenes at 8°C in the presence of NiCl2(PPh3)2 to give selectively the respective alkylated arenes in high yields. Addition of organic or inorganic bases lowers the reaction temperature to 50°C. (C) 2000 Elsevier Science Ltd.
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