Tetrahedron Letters p. 2157 - 2160 (2018)
Update date:2022-08-11
Topics:
Khomane, Navnath B.
Meshram, Harshadas M.
Rode, Haridas B.
Total synthesis of trocheliophorolide C epimer is reported. The synthetic strategy involves generation of lactone skeleton and preparation of unsaturated side chain followed by cross-metathesis. The Eglinton oxidative coupling, Cadiot-Chodkiewicz cross-coupling and cross-metathesis are the key reactions used in the synthesis. We also attempted the synthesis of trocheliophorolide D epimer, which includes Cu catalyzed various cross-coupling reactions.
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