Journal of Organometallic Chemistry p. 147 - 154 (1989)
Update date:2022-08-11
Topics:
Becker, B.
Corriu, R. J. P.
Guerin, C.
Henner, B. J. L.
Di and tri-hydrogenosilanes, RR'SiH2 and RSiH3 (R=aryl, allyl or benzyl; R'=aryl or alkyl), readily undergo exchange reactions, involving silicon-carbon bonds and silicon-hydrogen bonds, in the presence of hydrides (LiAlH4, KH and NaH) as catalysts.These results are discussed in terms of five-coordinate silicon hydrides as intermediates in the reaction.
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