Tetrahedron Letters p. 1539 - 1543 (2002)
Update date:2022-08-17
Topics:
Wu, Jing
Chen, Hua
Kwok, Wai Him
Lam, Kim Hung
Zhou, Zhong Yuan
Yeung, Chi Hung
Chan, Albert S.C
A new chiral dipyridylphosphine ligand Xyl-P-Phos has been synthesized and the structure of (S)-Xyl-P-Phos oxide has been characterized by single crystal X-ray diffraction. The ruthenium complex of this ligand, Ru(R-Xyl-P-Phos)(C6H6)Cl2, has been found to be a highly active, enantioselective and air-stable catalyst for the asymmetric hydrogenation of β-ketoesters and shows good potential for industrial applications.
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