Bulletin of the Chemical Society of Japan p. 3011 - 3013 (1988)
Update date:2022-08-29
Topics:
Hori, Yoji
Mitsudo, Take-aki
Watanabe, Yoshihisa
(1-2;5-6-η-Cyclooctadiene)(1-6-η-cyclooctatriene)ruthenium catalyzes the silylation of olefins at 60-140 deg C to give allylsilanes with good selectivity in high yields.The reactions of trialkylsilane with 2-methyl-1-butene, 2-methyl-2-butene, and 3-methyl-1-butene give the same product, 3-methyl-1-trialkylsilyl-2-butene.Silylation of ethyl (E)-2-butenoate gives ethyl (E)-4-trialkylsilyl-2-butenoate in high yield.
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