Phytochemistry p. 83 - 88 (1984)
Update date:2022-08-16
Topics:
Bellesia, Franco
Grandi, Romano
Pagnoni, Ugo M.
Pinetti, Adriano
Trave, Roberto
Iridodial is a key intermediate in the biosynthesis of nepetalactone.One of the steps on the pathway prior to the lactonization is a hydride shift from C-1 to C-10. 10-Hydroxycitronellol is a far more efficient precursor than the C-2/C-3 unsaturated analogue.Key Word Index -- Nepeta cataria; Labiatae; nepetalactone; iridane skeleton; monoterpene biosynthesis; hydride shift.
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