Page 7 of 10
Journal of the American Chemical Society
(12) Myroshnychenko, V.; RodríguezꢀFernández, J.; Pastorizaꢀ
different dendritic tethers was used to generate unprecedented
Santos, I.; Funston, A. M.; Novo, C.; Mulvaney, P.; LizꢀMarzán, L.
M.; García de Abajo, F. J. Chem. Soc. Rev. 2008, 37, 1792ꢀ1805.
(13) Choi, J. Y.; Kim, Y. T.; Seo, T. S. ACS Nano 2013, 7,
2627ꢀ2633.
(14) Mirkin, C. A.; Letsinger, R. L.; Mucic, R. C.; Storhoff, J. J.
Nature 1996, 382, 607ꢀ609.
(15) Elghanian, R.; Storhoff, J. J.; Mucic, R. C.; Letsinger, R.
L.; Mirkin, C. A. Science 1997, 277, 1078ꢀ1081.
(16) Macfarlane, R. J.; Lee, B.; Jones, M. R.; Harris, N.; Schatz,
G. C.; Mirkin, C. A. Science 2011, 334, 204ꢀ208.
(17) Sharma, J.; Chhabra, R.; Cheng, A.; Brownell, J.; Liu, Y.;
Yan, H. Science 2009, 323, 112ꢀ116.
(18) Lau, K. L.; Hamblin, G. D.; Sleiman, H. F. Small 2014, 10,
660ꢀ666.
(19) Lan, X.; Chen, Z.; Liu, B. J.; Ren, B.; Henzie, J.; Wang, Q.
Small 2013, 9, 2308ꢀ2315.
(20) Stamatoiu, O.; Mirzaei, J.; Feng, X.; Hegmann, T. Top.
Curr. Chem. 2012, 318, 331ꢀ394.
(21) Nealon, G. L.; Greget, R.; Dominguez, C.; Nagy, Z. T.;
Guillon, D.; Gallani, J.ꢀL.; Donnio, B. Beilstein J. Org. Chem. 2012,
8, 349ꢀ370.
(22) Lewandowski, W.; Wójcik, M.; Górecka, E. Chem-
physchem 2014, 15, 1283ꢀ1295.
(23) Saliba, S.; Mingotaud, C.; Kahn, M. L.; Marty, J.ꢀD. Na-
noscale 2013, 5, 6641ꢀ6661.
(24) Blanc, C.; Coursault, D.; Lacaze, E. Liq. Cryst. Rev. 2013,
1, 83ꢀ109.
(25) Chiu, J. J.; Kim, B. J.; Kramer, E. J.; Pine, D. J. J. Am.
Chem. Soc. 2005, 127, 5036ꢀ5037.
(26) Jones, M. R.; Osberg, K. D.; MacFarlane, R. J.; Langille,
M. R.; Mirkin, C. A. Chem. Rev. 2011, 111, 3736ꢀ3827.
(27) Wilner, O. I.; Willner, I. Chem. Rev. 2012, 112, 2528ꢀ2556.
(28) Srivastava, S.; Frankamp, B. L.; Rotello, V. M. Chem. Ma-
ter. 2005, 17, 487ꢀ490.
(29) Grayson, S. M.; Fréchet, J. M. J. Chem. Rev. 2001, 101,
3819ꢀ3868.
(30) Carlmark, A.; Hawker, C.; Hult, A.; Malkoch, M. Chem.
Soc. Rev. 2009, 38, 352ꢀ362.
(31) Newkome, G. R.; Shreiner, C. Chem. Rev. 2010, 110,
6338ꢀ6442.
(32) Sowinska, M.; UrbanczykꢀLipkowska, Z. New J. Chem.
2014, 38, 2168ꢀ2203.
(33) Gopidas, K. R.; Whitesell, J. K.; Fox, M. A. J. Am. Chem.
Soc. 2003, 125, 6491ꢀ6502.
(34) Bronstein, L. M.; Shifrina, Z. B. Chem. Rev. 2011, 111,
5301ꢀ5344.
(35) Daniel, M.ꢀC.; Astruc, D. Chem. Rev. 2004, 104, 293ꢀ346.
(36) Shon, YꢀS.; Choi, D. Curr. Nanosci. 2015, 3. 245ꢀ254.
(37) Advincula, R. C. Dalton Trans. 2006, 2778ꢀ2784.
(38) Fleutot, S.; Nealon, G. L.; Pauly, M.; Pichon, B. P.;
Leuvrey, C.; Drillon, M.; Gallani, J.ꢀL.; Guillon, D.; Donnio, B.;
BeginꢀColin, S. Nanoscale 2013, 5, 1507ꢀ1516.
(39) Donnio, B.; GarcíaꢀVázquez, P.; Gallani, J. L.; Guillon, D.;
Terazzi, E. Adv. Mater. 2007, 19, 3534ꢀ3539.
(40) Kanie, K.; Matsubara, M.; Zeng, X.; Liu, F.; Ungar, G.;
Nakamura, H.; Muramatsu, A. J. Am. Chem. Soc. 2012, 134, 808ꢀ811.
(41) Mischler, S.; Guerra S.; Deschenaux. R. Chem. Commun.
2012, 48, 2183ꢀ2185.
(42) Li, H.; Li, Z.; Wu, L.; Zhang, Y.; Yu, M.; Wei, L. Lang-
muir 2013, 29, 3943ꢀ3949.
(43) Brunetti, V.; Bouchet, L. M.; Strumia, M. C. Nanoscale
2015, 7, 3808ꢀ3816.
(44) Tekade, R. K.; Tekade, M.; Kumar, M.; Chauhan, A. S.
Pharm. Res. 2014, 32, 910ꢀ928.
(45) Park, M.ꢀH.; Kim, S. T.; Rana, S.; Solfiell, D.; Jeong, Y.;
Duncan, B.; Yan, B.; Aksoy, B.; Rotello, V. M. Nanoscale 2013, 5,
7805ꢀ7808.
1
2
3
4
5
6
7
8
complex singleꢀcomponent NP superlattices, and opens new
frontiers in the field of NPs assemblies. Indeed, this important
last result is very promising and motivates the exploration of
many other binary combinations of dendronized nanoparticuꢀ
late hybrids, considering various dendritic structures and peꢀ
ripheral groups, and expanding the range of inorganic cores to
different chemical compositions, sizes and shapes, to fabricate
more exotic and functional multicomponent superlattices i.e.
metamaterials with modulable and enhanced properties.
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
ASSOCIATED CONTENT
Supporting Information.
Full characterization of organic compounds, additional microscoꢀ
py, and supporting spectroscopy can be found in the Supporting
Information. This material is available free of charge via the
AUTHOR INFORMATION
Corresponding Author
*bdonnio@ipcms.unistra.fr
Present Address
¥Present address: Department of Chemical Engineering and
SUNCAT Center for Interface Science and Catalysis, Stanford
University, Stanford, CA 94305 (USA).
ACKNOWLEDGMENT
B. D. and D. J. thank the CNRS, UPENN and Solvay through the
COMPASS Lab in partnership with the Penn’s NSF MRSEC
under Award No. DMRꢀ112090. B. D. acknowledges additional
support from the ANR Programme blanc, METABIP, 12BS10ꢀ
003. Part of this work was supported by the Office of Naval Reꢀ
search MURI award No. ONRꢀN00014ꢀ10ꢀ1ꢀ0942. D. R. K.
acknowledges the Roy and Diana Vagelos Scholars Program in
the Molecular Life Sciences. C. B. M. acknowledges the Richard
Perry University Professorship.
REFERENCES
(1)
Redl, F. X.; Cho, K.ꢀS.; Murray, C. B.; O’Brien, S. Nature
2003, 423, 968ꢀ971.
(2)
Shevchenko, E. V; Talapin, D. V; Kotov, N. A; O’Brien,
S.; Murray, C. B. Nature 2006, 439, 55ꢀ59.
(3)
Xu, L.; Ma, W.; Wang, L.; Xu, C.; Kuang, H.; Kotov, N. A.
Chem. Soc. Rev. 2013, 42, 3114ꢀ3126.
(4)
Nie, Z.; Petukhova, A.; Kumacheva, E. Nat. Nanotechnol.
2010, 5, 15ꢀ25.
(5)
Dong, A.; Chen, J.; Vora, P. M.; Kikkawa, J. M.; Murray,
C. B. Nature 2010, 466, 474ꢀ477.
(6)
Talapin, D. V; Lee, J.ꢀS.; Kovalenko, M. V.; Shevchenko,
E. V. Chem. Rev. 2010, 110, 389ꢀ458.
(7)
Kovalenko, M. V.; Manna, L.; Cabot, A.; Hens, Z.; Taꢀ
lapin, D. V.; Kagan, C. R.; Klimov, V. I.; Rogach, A. L.; Reiss, P.;
Milliron, D. J.; GuyotꢀSionnnest, P.; Konstantatos, G.; Parak, W. J.;
Hyeon, T.; Korgel, B. A.; Murray, C. B.; Heiss, W. ACS Nano 2015,
9, 1012ꢀ1057.
(8)
Sönnichsen, C.; Reinhard, B. M.; Liphardt, J.; Alivisatos,
A. P. Nat. Biotechnol. 2005, 23, 741ꢀ745.
(9)
Storhoff, J. J.; Lazarides, A. A.; Mucic, R. C.; Mirkin, C.
A.; Letsinger, R. L.; Schatz, G. C. J. Am. Chem. Soc. 2000, 122,
4640ꢀ4650.
(10) Su, K. H.; Wei, Q. H.; Zhang, X.; Mock, J. J.; Smith, D. R.;
Schultz, S. Nano Lett. 2003, 3, 1087ꢀ1090.
(11) Jain, P. K.; Huang, W.; ElꢀSayed, M. A. Nano Lett. 2007,
7, 2080ꢀ2088.
(46) Walter, A.; Garofalo, A.; Parat, A.; Jouhannaud, J.; Pourꢀ
roy, G.; Voirin, E.; Laurent, S.; Bonazza, P.; Taleb, J.; Billotey, C.;
ACS Paragon Plus Environment