Communications
1
2
3
4
5
6
7
8
9
0
1
2
3
4
5
6
7
8
9
0
1
2
3
4
5
6
7
8
9
0
1
2
3
4
5
6
7
8
9
0
1
2
3
4
5
6
7
8
9
0
1
2
3
4
5
6
7
Catalytic Test
[4] F. Fanelli, G. Parisi, L. Degennaro, R. Luisi, Beilstein J. Org. Chem. 2017,
13, 520–542
Catalytic tests were performed in continuous-flow micro-reactor
[5] A. Nagaki, J. Catal. 2016, 13, 4690–4694
[6] X. Fan, G. Manchon, K. Wilson, S. Tennison, A. Kozynchenko, A. Lapkin,
P. Plucinski, J. Catal. 2009, 267, 114–120
(
ThalesNano H-Cube Proꢀ) that provides isothermal and isobaric
conditions within the operational range of pressure and temper-
ature up to 100 bar and 1508C. The catalyst (150 mg) was placed in
a stainless steel cartridge (70 mm CatCartꢃ) that enables a
continuous flow of hydrogen and citral solution through the
catalyst bed. The hydrogen was generated in situ via electrolysis of
water and then supplied to the reaction medium. The 0.05 M citral
ethanol solution was flown through the cartridge with
[
7] X. Fan, V. Sans, S. Sharma, P. Plucinski, V. Zaikovskii, K. Wilson, S.
Tennison, A. Kozynchenko, A. Lapkin, Catal. Sci. Technol. 2016, 6, 2387–
2
395
´
[8] M. Zienkiewicz-Machnik, I. Goszewska, A˛ . Sr e˛ bowata, A. Kubas. D.
Gizi n´ ski, G. Słowik, K. Matus, D. Lisovytskiy, M. Pisarek, J. Sꢄ, Catal. Today
2017, https://doi.org/10.1016/j.cattod.2017.08.062
[9] https://www.acs.org/content/dam/acsorg/sustainability/acsandsustain-
ability/sustainablemanufacturing/roadmaps/smrt-technology-area-4-
next-generation-chemical-manufacturing-pdf.pdf
À1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
4
4
4
4
4
4
4
4
4
4
5
5
5
5
5
5
5
5
0.5 mLmin .The residence time (defined as bed volume/flow rate)
was calculated to be 6 min. After attaining stable condition,
samples were collected at the outlet of the reactor and analyzed by
Bruker Scion 456-GC gas chromatograph equipped with FID
Analyzed compounds were separated with non-polar BP-5 0.25 mm
[
10] D. Gizi n´ ski, I. Goszewska, M. Zieli n´ ski, D. Lisovytskiy, K. Nikiforov, J.
´
Masternak, M. Zienkiewicz-Machnik, A. Sr e˛ bowata, J. Sꢄ, Catal. Commun.
2017, 98, 17–21
[
[
[
[
[
11] D. Pan, J. K. Jian, A. Ablat, J. Li, Y. F. Sun, R. Wu, J. Appl. Phys. 2012, 112,
(
5% phenyl/95% dimethyl polysiloxane) column.
0
53911
12] S. Wang, R. Shen, Z. Chen, J. Wang, D. Wang, Y. Li, Eur. J. Inorg. Chem.
2015, 2120–2124
13] J.-K. Kim, C.-S. Kang, J.-K. Lee, Y.-R. Kim, H.-Y. Han, H. K. Yun,
Entomological Res. 2005, 35, 117–120
14] K. Nakahara, N. S. Alzoreky, T. Yoshihashi, H. T. T. Nguyen, G. Trakoonti-
vakorn, Jpn. Agri. Res. Quart. 2003, 37, 249–252
15] a) W. G. Taylor, C. E. Schreck, J. Pharm. Sci. 1985, 74, 534–539; b) E. E.
Revay, D. L. Kline, R.-D. Xue, W. A. Qualls, R. Ulrich, V. D. Kravchenko, N.
Ghattas, I. Pstygo, G. C. Mꢅller, Acta Trop. 2013, 127,63–68; c) S.
Songkro, N. Hayook, J. Jaisawang, D. Maneenuan, T. Chuchome, N.
Kaewnopparat, J. Inclusion Phenom. Macrocyclic Chem. 2011, 72, 339–
Acknowledgements
The authors would like to thank the Polish National Science
Centre (NCN-OPUS 8 grant no. UMO-2014/15/BST5/02094) for the
financial support and Polish Ministry of Science and Higher
Education (budget allocations for science for years 2016–2019
within the IDEAS PLUS II project of number IdPII2015000164) for
the partial financial support.
3
55.
[
16] https://www.epa.gov/pesticides
[17] P. L. Alsters, W. Jary, V. Nadello-Rataj, J.-M. Aubry, Org. Process Res. Dev.
010, 14, 259–262
2
[
18] E. Bailꢆn-Garcia, F. Carrasco-Marin, A. Perez-Canedas, F. Maldonado-
Hꢆdar Catal. Commun. 2016, 82, 36–40
[19] P. Gallezot, D. Richard, Catal. Rev. Sci. Eng. 1998, 40, 81–126
20] a) X. Wang, W. Hu, B. Deng, X. Liang, J. Nanopart. Res. 2017, 19, 153;
b) X. Liu, Z. Zhang, Y. Yang, D. Yin, S. Su, D. Lei, J. Yang, Chem. Eng. J.
Conflict of Interest
[
The authors declare no conflict of interest.
2
015, 263, 290–298
[21] a) J. Stassi, P. Zgolicz, V. Rodrigez, S. Miguel, O. Scelza, Appl. Catal. A
015, 497, 58–71; b) Z. Tian, Q. Li, J. Hou, Y. Li, S. Ai, Catal. Sci. Technol.
2
Keywords: on-the-fly catalyst modification
·
structure-
2016, 6, 703–707
[
22] C. Liu, C. Nau, G. Fan, L. Yang, F. Li, J. Mol. Catal. 2017, 436, 237–247
performance relationship · hydrogenation · flow catalysis ·
´
´
[23] S. Grylkiewicz, A. Sliwak, J. Cwikła, G. Grylkiewicz, Can. J. Chem. Eng.
016, 94, 1328–1335
photon-in photon out spectroscopy
2
Manuscript received: April 6, 2018
Accepted Article published: June 14, 2018
Version of record online: &&&, &&&&
[
[
2] A. Tanimu, S. Jaenicke, K. Alhooshani, Chem. Eng. J. 2017, 327, 792–821
3] J. Britton, C. Roston, Chem. Soc. Rev. 2017, 46, 1250–1271
ChemCatChem 2018, -53, 1–7
www.chemcatchem.org
6
ꢁ 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
ÞÞ
These are not the final page numbers!