LIU RuiXia, et al. Sci China Chem July (2010) Vol.53 No.7
1577
1
1
4
5
Hammer B, Norskov JK. Why gold is the noblest of all the metals.
Nature, 1995, 376: 238–240
Zanella R, Louis C, Giorgio S, Touroude R. Crotonaldehyde hydro-
genation by gold supported on TiO : Structure sensitivity and mecha-
2
nism. J Catal, 2004, 223: 328–339
Liu F, Wechsler D, Zhang P. Alloy-structure-dependent electronic
behavior and surface properties of Au-Pd nanoparticles. Chem Phys
Lett, 2008, 461: 254–259
Cardenas-Lizana F, Gomez-Quero S, Keane M. Gas phase hydro-
genation of m-dinitrobenzene over alumina supported Au and Au-Ni
alloy. Catal Lett, 2009, 127: 25–32
Pawelec B, Cano-Serrano E, Campos-Martin JM, Navarro RM,
Thomas S, Fierro JLG. Deep aromatics hydrogenation in the presence
of DBT over Au-Pd/gamma-alumina catalysts. Appl Catal A, 2004,
drogenation of citral catalyzed with palladium nanoparticles in
CO -in-water emulsion. Green Chem, 2009, 11: 979–985
2
33 Zhao F, Ikushima Y, Shirai M, Ebina T, Arai M. Influence of electronic
state and dispersion of supported platinum particles on the conversion
and selectivity of selective hydrogenation of ,-unsaturated aldehyde
in supercritical carbon dioxide. J Mol Catal A, 2002, 180: 259–265
34 Arai M, Nishiyama Y, Ikushima Y. Optical absorption of fine gold
particles in supercritical carbon dioxide for the characterization of
solvent properties. J Supercrit Fluid, 1998, 13: 149–153
1
1
1
6
7
8
35 Bhanage BM, Ikushima Y, Shirai M, Arai M. The selective formation
of unsaturated alcohols by hydrogenation of ,-unsaturated alde-
hydes in supercritical carbon dioxide using unpromoted Pt/Al O3
2
catalyst. Catal Lett, 1999, 62: 175–177
36 Zhao F, Ikushima Y, Shirai M, Ebina T, Arai M. Influence of elec-
tronic state and dispersion of supported platinum particles on the
conversion and selectivity of selective hydrogenation of ,-unsatu-
rated aldehyde in supercritical carbon dioxide. J Mol Catal A, 2002,
2
75: 127–139
Venezia AM, La Parola V, Pawelec B, Fierro JLG. Hydrogenation of
aromatics over Au-Pd/SiO -Al catalysts; Support acidity effect.
Appl Catal A, 2004, 264: 43–51
Sarkany A, Geszti O, Safran G. Preparation of Pd-shell-Au-core/SiO
catalyst and catalytic activity for acetylene hydrogenation. Appl Catal
A, 2008, 350: 157–163
1
2
2
2
2
9
0
1
2
3
2
2 3
O
1
80: 259–265
2
3
7
Meric P, Yu KMK, Kong ATS, Tsang SC. Pressure-dependent prod-
uct distribution of citral hydrogenation over micelle-hosted Pd and
Ru nanoparticles in supercritical carbon dioxide. J Catal, 2006, 237:
0
Sarkany A, Hargittai P, Horvath A. Controlled synthesis of PDDA
stabilized Au-Pd bimetallic nanostructures and their activity in hy-
drogenation of acetylene. Top Catal, 2007, 46: 121–128
3
30–336
3
3
8
9
Poliakoff M, Howdle S. Supercritical chemistry: Synthesis with a
spanner. Chem Ber, 1995, 31: 118–121
Hiyoshi NV. Rode C, Sato O, Tetsuka H, Shirai M. Stereoselective
hydrogenation of tert-butylphenols over charcoal-supported rhodium
catalyst in supercritical carbon dioxide solvent. J Catal, 2007, 252:
Malinowski A. Hydrodechlorination of dichlorodifluoromethane
(CFC-12) on silica-supported palladium and palladium-gold catalysts.
Pol J Chem, 2002, 76: 1461–1466
Bonarowska M, Pielaszek J, Semikolenov VA, Karpinski Z.
Pd-Au/Sibunit carbon catalysts: Characterization and catalytic activ-
ity in hydrodechlorination of dichlorodifluoromethane (CFC-12). J
Catal, 2002, 209: 528–538
5
7–68
4
0
Hiyoshi N, Inoue TV. Rode C, Sato O, Shirai M. Tuning cis-decalin
selectivity in naphthalene hydrogenation over carbon-supported rho-
dium catalyst under supercritical carbon dioxide. Catal Lett, 2006,
2
2
2
2
4
5
6
7
Nutt MO, Heck KN, Alvarez P, Wong MS. Improved Pd-on-Au bi-
metallic nanoparticle catalysts for aqueous-phase trichloroethene hy-
drodechlorination. Appl Catal B, 2006, 69: 115–125
Venezia AM, La Parola V, Deganello G, Pawelec B, Fierro JLG.
Synergetic effect of gold in Au/Pd catalysts during hydrodesulfuriza-
tion reactions of model compounds. J Catal, 2003, 215: 317–325
Sarkany A, Horvath A, Beck A. Hydrogenation of acetylene over low
1
06: 133–138
41 Hiyoshi N, Mine EV, Rode C, Sato O, Shirai M. Stereoselective hy-
drogenation of tetralin to cis-decalin over a carbon-supported rho-
dium catalyst in supercritical carbon dioxide solvent. Chem Lett,
2006, 35: 188–189
42 Hiyoshi N, Mine EV, Rode C, Sato O, Shirai M. Low temperature
hydrogenation of tetralin over supported rhodium catalysts in super-
critical carbon dioxide solvent. Appl Catal A, 2006, 310: 194–198
43 Chatterjee M, Kawanami H, Sato M, Chatterjee A, Yokoyama T, Suzuki
T. Hydrogenation of phenol in supercritical carbon dioxide catalyzed by
palladium supported on Al-MCM-41: A facile route for one-pot cyclo-
hexanone formation. Adv Synth Catal, 2009, 351: 1912–1924
44 Ichikawa S, Tada M, Iwasawab Y, Ikariya T. The role of carbon di-
oxide in chemoselective hydrogenation of halonitroaromatics over
supported noble metal catalysts in supercritical carbon dioxide. Chem
Commun, 2005, 924–926
loaded Pd and Pd-Au/SiO
17–125
Liu R, Yu Y, Yoshida K, Li G, Jiang H, Zhang M, Zhao F, Fujita S,
Arai M. Physically and chemically mixed TiO -supported Pd and Au
catalysts: unexpected synergistic effects on selective hydrogenation
of citral in supercritical CO . J Catal, 2010, 269: 191–200
2
catalysts. Appl Catal A, 2002, 229:
1
2
2
2
8
Hao J, Xi C, Cheng H, Liu R, Cai S, Arai M, Zhao F. Influence of
compressed carbon dioxide on hydrogenation reactions in cyclohex-
ane with a Pd/C catalyst. Ind Eng Chem Res, 2008, 47: 6796–6800
Schwank J. Gold in bimetallic catalysts. Gold Bull, 1985, 18: 2–10
Milone C, Tropeano ML, Gulino G, Neri G, Ingoglia R, Galvagno S.
2
3
9
0
45 Liu H, Jiang T, Han B, Liang S, Zhou Y. Selective phenol hydro-
genation to cyclohexanone over a dual supported Pd-Lewis acid
catalyst. Science, 2009, 326: 1250–1252
2 3
Selective liquid phase hydrogenation of citral on Au/Fe O catalysts.
Chem Commun, 2002, 868–869
46 Augustine RL. Dekker Inc M, New York, 1996
3
3
1
2
Liu R, Zhao F, Fujita S, Arai M. Selective hydrogenation of citral
with transition metal complexes in supercritical carbon dioxide. Appl
Catal A, 2007, 316: 127–133
47 Chatterjee M, Chatterjee A, Ikushima Y. Pd-catalyzed completely
selective hydrogenation of conjugated and isolated C=C of citral
(3,7-dimethyl-2,6-octadienal) in supercritical carbon dioxide. Green
Chem, 2004, 6: 114–118
Liu R, Wu C, Wang Q, Ming J, Hao Y, Yu Y, Zhao F. Selective hy-