Bulletin of the Chemical Society of Japan p. 844 - 849 (1985)
Update date:2022-08-11
Topics:
Matsubara
Okazoe
Oshima
Takai
Nozaki
Isomerization of primary allylic alcohols proceeds in dichloromethane at 25 degree C in the presence of the catalyst prepared in situ from VO(acac)//2 or MoO//2(acac)//2, and Me//3SiOOSiMe//3 to give tertiary isomers in good yields. The catalysts are also effective for the rearrangements of sec. yields tert. allylic alcohols. The isomerization of an allenyl allylic alcohol, 6-methyl-1,2,5-heptatrien-4-ol, gives either (E)-2-methyl-3,5,6-heptarien-2-ol or (E)-6-methyl-3,5-heptadien-2-one selectively depending on the reaction conditions.
View MoreHangzhou GreenCo Science & Technology Co., Ltd.
Contact:86-571-88257303
Address:1713 Room,Jingui Building,Gudun Road,Xihu District,Hangzhou,China
website:http://www.chemdow.com
Contact:0086-10-82435335
Address:Room 401,Unit 3,4th Floor,Shangdijiayuan,Shangdi East Road, Haidian District,Beijing
Wuxi Forest Biological Co.,Ltd
Contact:+86-510-81602300
Address:Room 317,Building D, No.159 middle Chengjiang Road,Jiangyin Wuxi city.
Shanghai Gsyn Chemical Co.,Ltd.
Contact:86-021-67158290
Address:86-021-67158291
Contact:0550-7041128 0550-7090578
Address:Wangdian Street,Xinjie Town
Doi:10.1016/j.jcat.2005.11.025
(2006)Doi:10.1021/acs.organomet.6b00630
(2017)Doi:10.1111/j.1551-2916.2011.04486.x
(2011)Doi:10.1016/S0040-4020(01)88372-1
(1990)Doi:10.1016/j.orgel.2016.02.025
(2016)Doi:10.1021/acs.orglett.8b01658
(2018)