Synthesis p. 1157 - 1158 (1985)
Update date:2022-08-11
Topics:
Smith, Keith
Butters, Michael
Nay, Barry
t-Butyl hypochlorite supported on H(1+), Na(1+) faujasite X (zeolite X) produces para-selective monochlorination of alkyl-, phenyl-, and halobenzenes under mild conditions; for example, chlorobenzene in acetonitrile (at 40 deg C) is chlorinated in high yield of isolated product (92percent) to give dichlorobenzene with an isomer ratio 97percent para/3percent ortho.
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