Bulletin of the Chemical Society of Japan p. 3089 - 3093 (1991)
Update date:2022-08-11
Topics:
Kuroda, Yasushi
Kunai, Atsutaka
Hamada, Michiyuki
Kitano, Tomoyuki
Ito, Sotaro
Sasaki, Kazuo
Catalytic oxidation of naphthalene in moist acetic acid solutions has been studied.The catalyst used was a silica-supported palladium which works in cooperation with the Cu(1+)/Cu(2+) redox couple.Products were 1-naphthol, 1,4-naphthoquinone and (E)-2-formylcinnamaldehyde with a total yield of more than 78percent in which naphthoquinone shared 40percent.Reaction mechanism has been discused in comparison with that of benzene.
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