Synthetic Communications p. 3021 - 3026 (2005)
Update date:2022-08-17
Topics:
Ouk, Samedy
Thiebaud, Sophie
Borredon, Elisabeth
Chabaud, Bernard
Reactivity of dimethyl carbonate, the environmentally friendly reagent, as methylating agent for nitrogen-containing heterocyclic compounds has been studied. Reactions of imidazole, pyrazole, pyrrole, morpholine, and piperazine with dimethyl carbonate to afford N-methylated products were reported. The reactions were carried out with neither catalyst nor solvent at a temperature range of 110-170°C under atmospheric pressure. Copyright Taylor & Francis, Inc.
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