Journal of Molecular Catalysis A: Chemical p. 122 - 127 (2015)
Update date:2022-08-29
Topics:
Neubert, Peter
Steffen, Matthias
Behr, Arno
A convenient and selective access to saturated hexanoic esters via hydroesterification of piperylene with synthesis gas and methanol is presented. This is the first three step auto-tandem hydroesterification, which is 100% atom economic proceeding under mild conditions. Our optimisations revealed Pd2(dba)3/1,2-dtbpmb as the best catalytic system. Besides, the reaction also tolerates several alcohols, which offers a broad range of fruity esters. In addition, we present insights into the reaction sequence, investigating whether the reaction proceeds via two- or three-step reaction cascade.
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Doi:10.1021/ja01507a040
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