Bulletin of the Chemical Society of Japan p. 1707 - 1714 (1995)
Update date:2022-08-11
Topics:
Arai, Noriyoshi
Narasaka, Koichi
The one-electron oxidation of α-(arylazo)triphenylmethanes by cerium(IV) ammonium nitrate (CAN) generated aryl radicals along with the triphenylmethyl cation.When the reaction was carried out in the presence of appropriate radical-trapping agents, such as arenes and olefins, the corresponding addition products were obtained in moderate yield.The oxidation of the arylazo compounds with CAN was accelerated by the addition of acids.
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