Journal of Organometallic Chemistry p. 75 - 80 (2018)
Update date:2022-08-17
Topics:
Beppu, Teruo
Sakamoto, Kei
Nakajima, Yumiko
Matsumoto, Kazuhiro
Sato, Kazuhiko
Shimada, Shigeru
Hydrogenolysis of various halosilanes was catalysed by iridium amido complexes to produce hydrosilanes. Selective monohydrogenolysis of di- and trichlorosilanes similarly proceeded, resulting in the formation of chlorohydrosilanes (R2SiHCl or RSiHCl2) as synthetically important building blocks for various organosilicon compounds. A mechanistic study supported the in-situ formation of an iridium hydride species as a key intermediate, which could transfer the hydride to the silicon atom through a metal–ligand bifunctional mechanism. One-pot hydrotrimethylsilylation of olefins was achieved via successive hydrogenolysis and hydrosilylation reactions starting from Me3SiCl.
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