Tetrahedron Letters p. 2223 - 2226 (1995)
Update date:2022-08-17
Topics:
McKenna, Marie-Claire
Kim, Robert J.
McKenna, Charles E.
Cyclopropene 1, passed in a He stream through a gas chromatography column containing firebrick impregnated with a saturated solution of AgNO3 in glycerol, reacted to give acrolein 6 (6percent) and allyl nitrate 7 (20percent).The products were identified by GC, MS, IR, and 1H NMR.A mechanism is proposed to explain the reactions.
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