Journal of Physical Chemistry p. 4632 - 4636 (1988)
Update date:2022-08-25
Topics:
Yam, L. M.
Shultz, M. J.
Rock, Elizabeth J.
Buchau, Susanne
Results from the infrared laser-induced reaction of ethyl isocyanide indicate the overall behaviour to be similar to that of methyl isocyanide with some significant differences.Similarities include the following: (1) both exhibit a dramatic dependence of nitrile yield on reactant pressure, including a threshold pressure above which massive isomerization occurs; (2) this threshold pressure is not due to a thermal explosion; (3) both contain a radical channel along with the isomerization channel.Major differences between the methyl isocyanide and ethyl isocyanide reactions are attributable to the nature of the radicals in the particular isocyanide system.
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