Journal of the Chemical Society. Chemical communications p. 1290 - 1292 (1993)
Update date:2022-08-11
Topics:
Ruckenstein, Eli
Khan, Ashraf Z.
Promotion of CaO or MgO with various binary alkali metal compounds such as NaA + CsA, KA + CsA, LiA + CsA or LiA + NaA, where A = SO42-, OH-, Cl-, AcO-, CO32- or NO3-, leads to highly basic (superbasic) catalysts, which exhibit a noticeable synergistic effect compared with the effect produced by any monoalkali promoted system in the selective formation of acrylonitrile via oxidative methylation of acetonitrile with methane.
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