Chemistry Letters p. 1563 - 1566 (1988)
Update date:2022-08-11
Topics:
Ogura, Kotaro
Migita, Catharina T.
Yamada, Tooru
The photolysis of mixtures of CH4, NH3, and H2O with a low-pressure mercury lamp led to the formation of considerable amounts of methylamine and ethylenediamine with oxygen-containing compounds, ethane, and hydrogen.CH2NH2 radicals formed during photolysis were detected by ESR applying a spin trap technique, and it was suggested that the coupling of the radicals leads to the formation of ethylenediamine.
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