Tetrahedron Letters p. 4685 - 4688 (1987)
Update date:2022-08-16
Topics:
Gerdil, Raymond
Barchietto, Giacomo
Enantiomorphous tri-o-thymotide clathrates of prochiral oxiranes were submitted to the action of gaseous hydrogen halides.Ring-opening reactions ensued that differ from those reported in homogeneous phase, showing a considerable modification of the chemical reactivity of the external reagent in the host lattice.Chirality transfer from the host receptors to the guest products was also observed, but with a poor efficiency.
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