Chemistry Letters p. 679 - 682 (1982)
Update date:2022-08-16
Topics:
Izumi, Yusuke
Tanaka, Yoshiyuki
Urabe, Kazuo
The Keggin type heteropoly acid was readily reduced with hydrogen in the aqueous phase at 30 deg C in the presence of Pd(II) or metallic Pd, taking up 1 to 11 molecules of hydrogen per Keggin unit.The palladium catalyst prepared by the H2-reduction of an aqueous solution containing Pd(II) and heteropoly acid was very effective for the aqueous-phase selective semihydrogenation of propargyl alcohol.
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