Journal of labelled compounds and radiopharmaceuticals p. 1165 - 1174 (1994)
Update date:2022-08-11
Topics:
Lasne
Moreau
Cairon
Barre
Lithium aluminium hydride in the presence of vinylmagnesium bromide (1:1 molar ratio) affords a potent reagent for the reduction of acrylic acid to allyl alcohol (ratio of allyl alcohol to 1-propanol: 3:2). This reducing mixture has allowed the preparation of no-carrier added [1-11C]allyl alcohol with a 25% yield (decay corrected at the end of radionuclide production overall synthesis time including GC: 40 min in a one step procedure from [11C]carbon dioxide (C-11:t 1/2 : 20.4 min). [1-11C]1-propanol was obtained in parallel with a 6.5% yield.
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(1988)