Journal of Organometallic Chemistry p. 353 - 358 (1987)
Update date:2022-08-17
Topics:
Kundel, Peter
Berke, Heinz
Reaction of (OC)2ON<(i-PrO)3P>2WH (1) with acetic acid or phenol, respectively, yields an acetato or a phenolato complex (OC)nON<(i-PrO)3P>2WX; n = 1, X = CH3COO (2a); n =2, X = PhO (2b). 1 reduces aliphatic, α,β-unsaturated or aromatic aldehydes in the presence of acetic acid or phenol to yield alcohols in most cases.Crotonaldehyde reacts with 1 and phenol to produce butyraldehyde.
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