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Green Chemistry
DOI: 10.1039/C6GC01327A
ARTICLE
Journal Name
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8 K. Fabičovicová, O. Malter, M. Lucas and P. Claus, Green
o
MPa), reaction temperature (180-260 C), and reaction time
(
1-3 h). 1% Ru/WO
a complete conversion of cellulose and a top EG yield of 76.3%.
Detailed characterization of Ru/WO using several
3
was found to be an optimal promoter with
1
1
,
3
62-864.
physicochemical methods indicates that the high yield of EG
depends on a collective manufacture of the crystallinity and
Chem., 2014, 16, 3580-3588.
nature of the ruthenium particles, and the electronic 19 Z. Tai, J. Zhang, A. Wang, M. Zheng and T. Zhang, Chem.
interactions between tungsten oxide (WO
metallic sites. In addition, the presence of RuO
for the generation of protons and metallic Ru is favourable for
the reduction of WO to WO . Finally, a possible catalytic
reaction mechanism for the conversion of cellulose into EG 22 K. Fabičovicová, M. Lucas and P. Claus, Green Chem., 2015,
3
and WO
3
﹣
x
) and Ru
Commun., 2012, 48, 7052-7054.
20 Y. Liu, C. Luo and H. Liu, Angew. Chem. Int. Ed., 2012, 124,
δ
﹢
x
is responsible
3
303-3307.
1 M. Y. Zheng, A. Q. Wang, N. Ji, J. F. Pang, X. D. Wang and T.
Zhang, ChemSusChem, 2010, , 63-66.
2
3
3 x
﹣
3
over Ru/WO
3
catalyst was proposed. Further research will
17, 3075-3083.
3 Y. Cao, J. Wang, M. Kang and Y. Zhu, J. Mol. Catal. A: Chem.,
2
2
focus on the molecular comprehension of the complexation
between cellulose and tungsten trioxide, as well as kinetic
competition between glucose hydrogenation and retro-aldol
condensation involved in the composite catalyst systems.
2
014, 381, 46-53.
4 Z. Tai, J. Zhang, A. Wang, M. Zheng and T. Zhang, Chem.
Commun., 2012, 48, 7052-7054.
25 J. Zhang, B. Hou, A. Wang, Z. Li, H. Wang and T. Zhang, AIChE
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2
6 J. Zhang, X. Yang, B. Hou, A. Wang, Z. Li, H. Wang and T.
Zhang, Chin. J. Catal., 2014, 35, 1811-1817.
Acknowledgements
2
7 R. Ooms, M. Dusselier, J. A. Geboers, B. O. de Beeck, R.
Verhaeven, E. Gobechiya, J. A. Martens, A. Redl and B. F.
Sels, Green Chem., 2014, 16, 695-707.
This work was financially supported by the Fundamental
Research Funds for the Central Universities of China (No.
2
2
8 B. Kusserow, S. Schimpf and P. Claus, Adv. Synth. Catal.,
3207045403 and 3207045409), National Natural Science
2
003, 345, 289-299.
9 N. Li, H. Teng, L. Zhang, J. Zhou and M. Liu, RSC Adv., 2015,
5394-95400.
Foundation of China (No. 21576050), Jiangsu Provincial Natural
Science Foundation of China (BK20150604) and A Project
5,
9
Funded by the Priority Academic Program Development of 30 G. Zhang, W. Guan, H. Shen, X. Zhang, W. Fan, C. Lu, H. Bai, L.
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