Tetrahedron Letters p. 6923 - 6926 (1995)
Update date:2022-08-11
Topics:
Iwahama, Takahiro
Sakaguchi, Satoshi
Nishiyama, Yutaka
Ishii, Yasutaka
Aerobic oxidation of various alcohols has been accomplished by using a new catalytic system. N-hydroxyphthalimide (NHPI) combined with Co(acac)3. The oxidation of alcohols by NHPI was found to be markedly enhanced by adding a slight amount of Co(acac)3 (0.05 equiv. to NHPI). Thus, secondary alcohols and vic-diols which are difficult to be oxidized by NHPI alone were smoothly oxidized with molecular oxygen (1 atm) to the corresponding carbonyl compounds under relatively mild conditions (65 ~ 75 °C).
View MoreTai zhou world Pharm & Chem Co., Ltd
Contact:+86-576-85301198
Address:Rome 1001,wangjiang plaza,unti 2,jinshan east Road linhai,zhejiang,china
Springchem New Material Technology Co.,Limited
website:http://www.spring-chem.com
Contact:86-21-62885108
Address:602B, Building 1, No. 641, Tianshan Road
Shandong Zhongcheng Barium Salt Co., Ltd
Contact:+86-15725732638
Address:No.29 baoxi road, hi-tech zone, zibo, shandong
Contact:+86-25-8776 0031
Address:3-2001 Jiaye Int'l Town, 158 Lushan Road,Nanjing, 210019, China
Jiande City Silibase Silicone New Material Manufacture Co., Ltd.
Contact:15967177856
Address:Genglou Industrial Development Area
Doi:10.1248/cpb.38.276
(1990)Doi:10.1021/ja01651a058
(1954)Doi:10.1021/acs.inorgchem.9b02252
(2019)Doi:10.1007/s11164-021-04507-6
(2021)Doi:10.1248/cpb.c17-00907
(2018)Doi:10.1021/ol0357696
(2003)