Organometallics
Communication
difficult C−H activation reactions and its activity is comparable
(h) Schultz, K. M.; Goldberg, K. I.; Gusev, D. G.; Heinekey, D. M.
Organometalics 2011, 30, 1429.
to that of other reported systems.
(
9) (a) Fan, L.; Parkin, S.; Ozerov, O. V. J. Am. Chem. Soc. 2005, 127,
6772. (b) For recent work from our group utilizing the [PNP]Ir
framework, see: Whited, M. T.; Grubbs, R. H. Acc. Chem. Res. 2009,
2, 1607 and references cited therein.
10) For selected examples, see: (a) Sommer, L. H.; Lyons, J. E.
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ASSOCIATED CONTENT
Supporting Information
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Text, a table, and figures giving detailed experimental
procedures and characterization data for new compounds.
J. Am. Chem. Soc. 1968, 90, 4199. (b) Harrod, J. F.; Gilson, D. F. R.;
Charles, R. Can. J. Chem. 1969, 47, 2205. (c) Gregg, B. T.; Cutler, A. R.
Organometallics 1993, 12, 2006. (d) Campos, J.; Esqueda, A. C.;
Lop
Maya, C.; Carmona, E. J. Am. Chem. Soc. 2010, 132, 16765.
e) Fortman, G. C.; Jacobsen, H.; Cavallo, L.; Nolan, S. P. Chem.
Commun. 2011, 47, 9723.
11) (a) Calimano, E.; Tilley, T. D. J. Am. Chem. Soc. 2009, 131,
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ez-Serrano, J.; Sanchez, L.; Cossio, F. P.; de Cozar, A.; Alvarez, E.;
AUTHOR INFORMATION
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1161. (b) Calimano, E.; Tilley, T. D. Organometallics 2010, 29, 1680.
ACKNOWLEDGMENTS
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(12) Foley, P.; DiCosimo, R.; Whitesides, G. M. J. Am. Chem. Soc.
Generous financial support of this research was provided by BP
1980, 102, 6713.
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(MC initiative). A.F. thanks the Swiss National Science
NOTE ADDED AFTER ASAP PUBLICATION
In the version of this paper that was published on December
15, 2011, two footnotes were inadvertently left out of Table 1.
The version that appears as of December 20, 2011, is correct.
Foundation for a postdoctoral fellowship.
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dx.doi.org/10.1021/om201049p | Organometallics 2012, 31, 39−41