Synlett p. 801 - 802 (1997)
Update date:2022-08-16
Topics:
Sawamura, Masaya
Kawaguchi, Yasuhide
Nakamura, Eiichi
In the presence of near stoichiometric amount of molecular oxygen, various alkyl halides were converted to the corresponding alcohols in high yields through aerobic radical reaction promoted by a Bu2(t-Bu)SnCl/NaBH3CN catalytic system. Isotope-labeled alcohols were prepared with 18O2 and 17O2 without loss of the isotopic purities of the starting oxygen gases.
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