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Experimental details of data acquisition and additional disꢀ
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AUTHOR INFORMATION
Corresponding Author
glorius@uniꢀmuenster.de
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Notes
(4) For reviews on Rh(III)ꢀcatalyzed C−H activations, see: (a)
Colby, D. A.; Bergman, R. G.; Ellman, J. A. Chem. Rev.
2010, 110, 624. (b) Satoh, T.; Miura, M. Chem. Eur. J.
2010, 16, 11212. (c) Song, G.; Wang, F.; Li, X. Chem. Soc.
Rev. 2012, 41, 3651. (d) Colby, D. A.; Tsai, A. S.; Bergman,
R. G.; Ellman, J. A. Acc. Chem. Res. 2012, 45, 814. (e)
Patureau, F. W.; WencelꢀDelord, J.; Glorius, F. Aldrichim.
Acta, 2012, 45, 31. (f) Kuhl, N.; Schröder, N.; Glorius, F.
Adv. Synth. Catal. 2014, 356, 1443. (g) Song, G.; Li, X. Acc.
Chem. Res. 2015, 48, 1007. (h) Ye, B.; Cramer, N. Acc.
Chem. Res. 2015, 48, 1308.
The authors declare no competing financial interest.
ACKNOWLEDGMENT
The authors acknowledge financial support from the Alexꢀ
ander von Humboldt Foundation (X.W.) and Deutsche Forꢀ
schungsgemeinschaft (Leibniz Award). The authors are
grateful to Frederik Sandfort for experimental assistance.
The authors also thank Dr. Manuel van Gemmeren, Dr.
Christian MückꢀLichtenfeld and Suhelen VásquezꢀCéspedes
(all WWU Münster) for helpful discussions.
(5) For reviews of oxidizing directing groups, see: (a) Sun, H.;
Huang, Y. Synlett 2015, 26, 2751. (b) Mo, J.; Wang, L.; Liu,
Y.; Cui, X. Synthesis 2015, 47, 439. (c) Huang, H.; Ji, X.;
Wu, W.; Jiang, H. Chem. Soc. Rev. 2015, 44, 1155.
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