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13. Typical experimental procedure:- In
a 100 mL stainless steel
autoclave, diol (5 mmol), catalyst (10 % Pd/C, 0.5 mol%), KI (0.09
mmol), base (1.25 mmol), solvent (10 mL) were added. The autoclave
was closed, flushed with nitrogen, pressurized with O2 (33 psi) and
CO (167 psi) and the reaction mixture was stirred with a mechanical
starrer (520 rpm) at desired temperature for appropriate time period.
After completion of reaction, the reactor was then cooled to room
temperature, degassed carefully and opened. The reaction mixture
was filtered and the solvent was evaporated under vacuum. The
reaction mixture was analyzed by GC analysis (Perkin-Elmer, Clarus
400) equipped with a flame ionization detector (FID) and a capillary
column (Elite-1, 30 m × 0.32 mm × 0.25 µm). Purification of residue
was carried out by column chromatography (silica gel 100–200 mesh,
petroleum ether/ethyl acetate) to afford the corresponding products in
good to excellent yield. The prepared compounds were characterized
by 1H NMR (Varian 200 MHz NMR Spectrometer), 13C NMR spectra
(50 MHz) and GC-MS (Shimadzu GC-MS QP 2010) (Rtx-17, 30 m ×
25mmID, film thickness 0.25 µm df) (column flow- 2 mL/min, 80 °C
to 240 °C at 10°/min. rise.) which were consistent with those reported
in the literature.