Journal of the Chemical Society - Faraday Transactions p. 4381 - 4386 (1993)
Update date:2022-08-16
Topics:
Vatti, Francesco P.
Forni, Lucio
The temperature-programmed desorption-reaction (TPDR)-mass spectrometry (MS) technique has been employed to study the behaviour and the reactivity of the title reactant mixture over a catalyst of amorphous silica-alumina impregnated with Sb2O3 and CuO.This catalyst exhibited acidic and redox properties, leading to oxidation, dehydration and alkylation reactions.The formation of 2,6-lutidine takes place only at high temperature, requiring a high activation energy.The reaction mechanism involves alkylation of acetone by methanol to form methyl ethyl ketone, followed by reaction of the latter with ammonia to form an imine, then reaction of the imine with a second molecule of acetone, and finally, cyclisation to 2,6-lutidine.
View MoreJiande City Silibase Silicone New Material Manufacture Co., Ltd.
Contact:15967177856
Address:Genglou Industrial Development Area
Changzhou Litong Chemical Co., Ltd.
website:http://www.litonchem.com/
Contact:+86-519-86301238
Address:Laoba Rd, Hutang town Changzhou Jiangsu
Nanjing Samwon International Limited
Contact:+86-25-84873444
Address:1108, BLDG B, New Century Plaza, No 1, South Taiping Rd.,
Zhejiang Bolaite Technology Co.,Ltd
Contact:+86-0570-6523168 +86-0570-6523150
Address:No.5 YinKeng Road Kaihua Industrial Park(Chengguan Town) Zhejiang Prov.
website:http://www.arromax.com
Contact:+86-0512-62959601 skype:aimmezhang
Address:Suite 401, Bldg A3, 218 Xinghu St.Suzhou Industrial Park 215123, P.R. China
Doi:10.1016/j.ica.2011.06.041
(2011)Doi:10.1002/adsc.201900530
(2019)Doi:10.1007/s11426-012-4663-1
(2012)Doi:10.1002/jhet.4264
(2021)Doi:10.1039/jr9490001034
(1949)Doi:10.1039/c39890000790
(1989)