Tetrahedron Letters p. 3097 - 3100 (1990)
Update date:2022-08-11
Topics:
Barton, Derek H. R.
Csuhai, Eva
Doller, Dario
Ozbalik, Nubar
Senglet, Nathalie
A precise comparison has been made between radical bromination of a series of saturated hydrocarbons using BrCCl3 and the bromination of the same series with the same reagent under Gif-type (GoAggIII) conditions. The relative reactivities in the two series are completely different and confirm a difference in mechanism. Experiments with n-butane and with propane have shown that these gases react with the usual Gif selectivity to furnish 2-butanone and acetone respectively.
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