Industrial and Engineering Chemistry, Process Design and Development p. 215 - 218 (1976)
Update date:2022-08-11
Topics:
Matsumoto
Furukawa
Tanaka
Yano
Kamita
Naphthalene was selectively hydrogenated to tetralin, followed by reaction with styrene to give 1-phenyl-1-tetrahydronaphthylethane in 87% yield. Efficient catalysts for the reaction were 90% sulfuric acid or solid acids possessing acid sites of H//0 less than or equal to minus 5. 6. Purified 1-phenyl-1-tetrahydronaphthylethane has favored properties for a high boiling point thermal transfer fluid: boiling point, 342 C; pour point minus 37. 5 C; good thermal stability, etc. On severe heating, it decomposed to low fractions to some extent with little tendency to polymerization.
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