Journal of Organometallic Chemistry p. C4 - C8 (1989)
Update date:2022-08-24
Topics:
Rahm, A.
Amardeil, R.
Degueil-Castaing, M.
The use of the high pressure technique enables reduction of organic halides by tri-n-butyltin hydride to be carried out in the absence of a catalyst or free radical initiator.It leads to a better conservation of the structure of the starting material during the reduction.In the case of some unsaturated halides, a new chemoselectivity has been observed in favour of the addition of the hydride on the carbon-carbon double bond.
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